Bis[(2-pyridyl)(2-pyridylamino)methanolato]manganese(III) nitrate
نویسندگان
چکیده
The Mn(III) atom in the title complex, [Mn(C(11)H(10)N(3)O)(2)]NO(3), is coordinated by the two tridentate (2-pyrid-yl)(2-pyridyl-amino)-methano-late ligands, forming a six-coordinate environment. The four pyridyl N atoms constitute the equatorial plane on which the manganese(III) ion lies; the coordination plane suffers a slight distortion as indicated by the average plane deviation of 0.058 Å. The methano-late O atoms occupy the axial positions. The coordination geometry is thus octa-hedral. In the title compound, the cations are linked by nitrate anions via N-H⋯O hydrogen bonds to form one-dimensional chains. Moreover, the one-dimensional structure is stabilized by inter-molecular edge-to-face aromatic π-π inter-actions with a center-of-inversion at a distance of ca 4.634 Å.
منابع مشابه
Bis{4-chloro-N′-[phenyl(2-pyridyl)methylidene]benzohydrazidato-κ2 N′,O}cobalt(III) nitrate methanol disolvate
In the title compound, [Co(C(19)H(13)ClN(3)O)(2)]NO(3)·2CH(3)OH, the central Co(III) atom in the cation is surrounded by two tridentate ligands in a distorted octa-hedral fashion by four N and two O atoms. Classical O-H⋯O hydrogen bonds link both methanol solvent mol-ecules with the nitrate anion.
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متن کامل{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4 N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)
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متن کامل[Bis(2-pyridyl)amine-N,N′](nitrato-O,O′)cobalt(II) nitrate. Corrigendum
The chemical name and formula in the paper by Castillo, Luque, De la Pinta & Román [Acta Cryst. (2001), E57, m384-m386] is corrected.[This corrects the article DOI: 10.1107/S1600536801012909.].
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011